SwitchbladeThe primary use of lead in gas was for valve cushioning ..
Negative... primary use of tetraethyl lead was for knock or detonation
control...
The story how lead got into our fuels started with high compression
aircraft engines back in 1921... a young engineer fresh out of college
named Charles Kettering started Dayton Engineering Labs Company or Delco...
he invented the first battery ignition systems for aircraft engines...
when protagonists in the field of aviation widely blamed his battery
ignition systems on knock or detonation Kettering commanded his young
assistant Thomas A. Midgley on a investigation of detonation.
motivated as much by a desire to protect Delco's reputation as by
scientific altruism. Midgley worked for months over his single
cylinder engine and famous "bouncing pin" which was devised to measure
differences in detonation pressures. and he soon determined that
detonation depended on both fuel grade and engine compression ratio.
Thinking at first that fuel color influenced knock. Midgley added
iodine to his fuel theorizing a dark-colored fuel would absorb more
heat energy and vaporize more quickly. When the knock diminished he
smelled success, but it did not come in the form . he suspected.
Further experiments forced him to discard the fuel color idea but led
in turn to a long. frustrating line of trial anti-knock additives. GM.
parent company of Delco. encouraged Midgley and his assistant T. A.
Boyd. who in a vigorous program, individually tested more than 30,000
compounds and their discouragement mounted with the list. On December
9, 1921. a chilly Friday. Midgley and Boyd were anticipating the
weekend's respite from their series of relentless, routine tests when
suddenly the engine was not behaving the same at all. Jolted into
disbelief, Midgley had quite literally stumbled onto the remarkable
antiknock properties of an obscure substance called tetraethyl lead.
This proved to be without doubt the greatest single discovery in the
development of aviation fuels; not only did this additive make higher
power possible. it enabled the aircraft to fly farther on a given
amount of fuel- it gave aircraft range and in turn enabled the
successful engines that dominated aviation until the advent of gas
turbines.
Thomas Midgley
[image: thomas-midgley-jr-12.jpeg]
Charles Kettering
[image: Time-magazine-cover-charles-kettering.jp]